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The aim of this study was to determine the properties of liquid and cured UF (urea-formaldehyde) resin modified with pMDI (polymeric 4, 4′-methylenediphenyl isocyanate). Analyses showed that when introduced to liquid UF resin already at 10 %, its reactivity increases, which is reflected in a shortening of gel time and reduction of activation energy of the polycondensation process. In turn, analyses performed on polycondensed resin showed that, thanks to modification with pMDI, its hydrophobicity is considerably improved, as manifested in a reduction of absorbability and swelling in thickness of cured resin.Cilj istraživanja bio je utvrditi svojstva tekuće i otvrdnute UF smole (urea-formaldehida) modificirane s pMDI-jem (polimernim 4, 4′-metilendifenil izocijanatom). Analiza je pokazala da dodavanjem pMDI-jatekućoj UF smoli već u 10 %-tnoj količini rezultira povećanjem reaktivnosti, izraženoj skraćivanjem vremena želiranja i smanjenjem energije aktiviranja procesa polikondenzacije. Osim toga, analiza svojstava polikondenzirane smole pokazala je da je, zahvaljujući modifikaciji s pMDI-jem, znatno poboljšana hidrofobnost, što se očituje smanjenjem apsorpcije i bubrenja otvrdnute smole u debljinu

Properties of Liquid and Polycondensed UF Resin Modified with pMDI