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In this study, the photocatalytic decomposition characteristics of single toluene, toluene mixed with benzene, toluene mixed with acetone, and toluene mixed methyl mercaptan (MM) by UV reactor installed with TiO 2 -coated perforated plate were studied. The photocatalytic decomposition rate of single toluene, toluene mixed with benzene, toluene mixed with acetone, and toluene mixed with MM fitted well on Langmuir-Hinshelwood (L-H) kinetics equation. The maximum elimination capacity was obtained to be 628 g/m 3 ·d for single toluene, 499 g/m 3 ·d for toluene mixed with benzene, 318 g/m 3 ·d for toluene mixed with acetone, and 513 g/m 3 d for toluene mixed with MM, respectively. The negative effect in photocatalytic decomposition of toluene are found to be in the order of acetone>benzene>MM. Key words : Photocatalytic decomposition, Acetone, Benzene, Toluene, Methyl mercaptan 1) 1.                  (Volatile Organic Compounds, VOCs)    (Jeon , 2013). VOCs      ,     , ,   (Wen , 2009).            , , MM     ,      (Kim , 2004).    (Buzek , 1999) (Lee , 2012), (Everaert Baeyens, 2004), (Lee , 2003)   (Zhang , 2006)    .       VOCs        .      ,

Effect of Benzene, Acetone, and Methyl Mercaptan Vapor on Photocatalytic Decomposition of Toluene Vapor