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The condensation of several aromatic/heteroaromatic aldehydes with 2-aminothiophenol under melt reaction conditions afforded 2-arylbenzothiazoles under solvent-free conditions. The major advantages of the present method are high yields, short reaction times, and eco-friendly conditions

Solvent- and catalyst-free synthesis of 2-aryl(heteroaryl)-substituted benzothiazoles