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The interaction of lanthanide nitrates (Ln–Nd, Sm, Dy and Er) and 1.10–phenantroline were studied and complexes of the general formulae Ln(NO3)3(C12H8N2)2 or Ln(NO3)3(o-fen)2. The complexes were characterized by elemental analyses (CHN), titration with EDTA, IR spectra and thermogravimetric analysis. X-ray powder patterns further indicated that the complexes are isomorphous having the same d -interplanar spacing.

1.10 – PHENANTHROLINE COMPLEXES OF THE RARE EARTH NITRATE: SYNTHESIS AND CHARACTERIZATION.