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Total organic carbon (TOC) content, total nitrogen (TN) content, elemental (C and N), and isotopic (d13C-TOC) composition of organic matter derived from both marine and terrestrial sources constrain the relative contributions from marine productivity, the mangroves, and the continental wind erosion of 36 carbonate-free surface sediments along the southwestern coast of the Baja California Peninsula. In general, the spatial patterns of TOC, TN, C:N ratio and d13C-TOC are similar. The maximum content of TOC (14.5%) and TN (1.6%) were measured inside the oxygen minimum zone (OMZ). The stable carbon isotopic compositions were enriched in 12C in surface sediments at suboxic sites within the OMZ. The C:N ratio and δ13C-TOC values indicated that the organic sediment material is predominantly of marine origin, with a minor contribution from the terrestrial source or mangroves. In the stations near to the coast, the high values of the C:N ratio and the depleted 13C values suggest a proportionally greater accumulation of terrestrial organic matter. The terrestrial-derived organic carbon content is <10% at the continental margin and >40% at the stations near to the coast, based on a Mixing Model of End Members.El contenido de carbono orgánico total (COT), nitrógeno total (NT), la composición elemental (C y N) e isotópica derivada de fuentes marina y terrestre ha permitido delimitar la contribución relativa de la productividad marina, los manglares y la erosión continental (eólicos) de 36 muestras de sedimentos superficiales (libres de carbono inorgánico) en el margen SW de Baja California. En general, la distribución espacial de COT, NT, la razón C:N y el d13C-COT son similares. El contenido máximo de COT (14.5%) y NT (1.6%) fue observado dentro de la zona de oxígeno mínimo. La composición isotópica de carbono está enriquecida en 12C en sedimentos superficiales de sitios subóxicos dentro de la ZOM. La razón C:N y los valores del d13C-COT indicaron que el material orgánico en sedimentos es predominantemente de origen marino con una menor contribución terrestre o de manglar. En las estaciones cercanas a la costa, los mayores valores de la razón C:N y los valores empobrecidos en 13C sugieren una acumulación mayor de materia orgánica terrestre. El contenido de carbono orgánico derivado de origen terrestre es <10% en el margen continental y >40% en estaciones cercanas a la costa sobre la base del modelo de mezcla de “end-members”

journal of iberian geology

Distribution and composition of organic matter in sediments of the oxygen minimum zone of the Northeastern Mexican Pacific: paleoceanographic implications.