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. Leaching of dissolved organic carbon (DOC) from soils into the river network is an important component of the land carbon (C) budget. At regional to global scales, its significance has been estimated through simple mass budgets, often using multi-year averages of observed fluvial DOC fluxes as a proxy of DOC leaching due to the limited availability of observations of the leaching flux itself. This procedure leads to a systematic underestimation of the leaching flux because of the decay of DOC during fluvial transport. Moreover, this procedure does not allow for revealing spatiotemporal variability in DOC leaching from soils, which is vital tobetter understand the drivers of DOC leaching and its impact on the localsoil C budget. In this study, we use the land surface model (LSM) ORCHILEAK to simulate the terrestrial C budget, including leaching of DOC from the soil and its subsequent reactive transport through the river network of Europe. The model performance is evaluated not only against the sparse observations of the soil DOC leaching rate, but also against the more abundant observations of fluxes and reactivity of DOC in rivers, providing further evidence that our simulated DOC fluxes are realistic. The model is then used to simulate the spatiotemporal patterns of DOC leaching across Europe over the period 1972–2012, quantifying both the environmental drivers of these patterns and the impact of DOC leaching on the land C budget. Over the simulation period, we find that, on average, 14.3 Tg C yr−1 of DOC is leached from land into European rivers, which is about 0.6 % of the terrestrial net primary production (NPP), a fraction significantly lower than that reported for tropical river networks. On average, 12.3 Tg C yr−1 of the leached DOC is finally exported to the coast via the river network, and the rest is respired during transit. DOC leaching presents a large seasonal variability, with the maximum occurring in winter and the minimum in summer, except for most parts of northern Europe, where the maximum occurs in spring due to snowmelt. The DOC leaching rate is generally low in warm and dry regions, and high in the cold and wet regions of Europe. Furthermore, runoff and the ratio between runoff from shallower flow paths on one hand and deep drainage and groundwater flow on the other hand are the main drivers of the spatiotemporal variation of DOC leaching. Temperature, as a major control of DOC production and decomposition rates in the soils, plays only a secondary role.

Spatiotemporal patterns and drivers of terrestrial dissolved organic carbon (DOC) leaching into the European river network