English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The traditional kinetics of electronically excited products of O3 andO2 photolysis is supplemented with the processes of the energy transferbetween electronically-vibrationally excited levels O2(a1Δg, v) and O2(b1Σ+g, v), excited atomicoxygen O(1D), and the O2 molecules in the ground electronic stateO2(X3Σg−, v). In contrast to the previous modelsof kinetics of O2(a1Δg) and O2 (b1Σ+g), our model takes into consideration the following basicfacts: first, photolysis of O3 and O2 and the processes of energyexchange between the metastable products of photolysis involve generation ofoxygen molecules on highly excited vibrational levels in all consideredelectronic states – b1Σ+g, a1Δgand X3Σg−; second, the absorption of solar radiationnot only leads to populating the electronic states on vibrational levelswith vibrational quantum number v equal to 0 – O2(b1Σ+g, v=0) (at 762 nm) and O2(a1Δg, v=0)(at 1.27 µm), but also leads to populating the excitedelectronic–vibrational states O2(b1Σ+g, v=1)and O2(b1Σ+g, v=2) (at 689 nm and 629 nm). Theproposed model allows one to calculate not only the vertical profiles of theO2(a1Δg, v=0) and O2(b1Σ<sup+g, v=0) concentrations, but also the profiles of[O2(a1Δg, v≤5)], [O2 (b1Σ+g , v=1, 2)] and O2(X3Σg−, v=1–35). In the altitude range 60–125 km, consideration of theelectronic-vibrational kinetics significantly changes the calculatedconcentrations of the metastable oxygen molecules and reduces the discrepancybetween the altitude profiles of ozone concentrations retrieved from the 762-nm and 1.27-µm emissions measuredsimultaneously

annales geophysicae

Model of daytime emissions of electronically-vibrationally excited products of O&amp;lt;sub&amp;gt;3&amp;lt;/sub&amp;gt; and O&amp;lt;sub&amp;gt;2&amp;lt;/sub&amp;gt; photolysis: application to ozone retrieval