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Formation of binary cluster ions from polar vapours is considered. Theeffect of vapour polarity on the size and composition of the criticalclusters is investigated theoretically and a corrected version of classicalKelvin-Thomson theory of binary ion-induced nucleation is derived. The modelpredictions of the derived theory are compared to the results given byclassical binary homogeneous nucleation theory and ion-induced nucleationtheory. The calculations are performed in wide range of the ambientconditions for a system composed of sulfuric acid and water vapour. It isshown that dipole-charge interaction significantly decreases the size of thecritical clusters, especially under the atmospheric conditions when the sizeof critical clusters is predicted to be small

Formation of binary ion clusters from polar vapours: effect of the dipole-charge interaction