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. This article, the eighth in the series, presents kinetic andphotochemical data sheets evaluated by the IUPAC Task Group on AtmosphericChemical Kinetic Data Evaluation. It covers the gas-phase thermal andphotochemical reactions of organic species with four, or more, carbon atoms(≥ C4) available on the IUPAC website in 2021, including thermalreactions of closed-shell organic species with HO and NO3 radicals andtheir photolysis. The present work is a continuation of volume II (Atkinsonet al., 2006), with new reactions and updated data sheets for reactions of HO(77 reactions) and NO3 (36 reactions) with ≥ C4 organics,including alkanes, alkenes, dienes, aromatics, oxygenated, organic nitratesand nitro compounds in addition to photochemical processes for nine species.The article consists of a summary table (Table 1), containing the recommended kineticparameters for the evaluated reactions, and a supplement containing thedata sheets, which provide information upon which recommendations aremade.

atmospheric chemistry and physics

Evaluated kinetic and photochemical data for atmospheric chemistry: volume VIII – gas-phase reactions of organic species with four, or more, carbon atoms ( ≥ C&amp;lt;sub&amp;gt;4&amp;lt;/sub&amp;gt;)