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The titled bifunctional fiber (FVCPS-f) were prepared by treating chloromethylated vinylbiphenyl-grafted polyethylene-coated polypropylene fiber (0.9 denier, length 3.8cm) with triethyl phosphite, chlorosulfonic acid, and conc. hydrochloric acid, in successive. Phosphorus and sulfur contents of FVCPS-f were 1.8 and 0.74 mmol/g, respectively and its acid capacity was 4.2 meq/g. Its breakthrough capacity (BC) for Fe (III) gradually decreased with an increase in flow rate of feeds from 20 to 1000 h-1 in space velocity (SV) ; for instance, its BC at a SV 1000 h-1 was 0.12 mmol/g, whereas commercially available phosphonate resin and monofunctional phosphonate fiber were not able to give practically meaningful BC at such an extremely high flow rate.

Bifunctional Phosphonate Fiber Derived from Vinylbiphenyl-grafted Polyethylene-coated Polypropylene Fiber for Extremely Rapid Removal of Iron (III)