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Inorganic microballoons composed of metal-silicate shell were prepared by ion exchange between internal Na+ and external metal cation through liquid surfactant membrane. The effects of metal species and salts concentration on the state of microballoons were examined for a series of alkaline earth and transition metals. The mechanism of balloons formation was discussed based on the ion releasing behavior and the composition of particles.

Preparation of Metal-Silicate Microballoons Based on Ion Exchange through Liquid Surfactant Membrane