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• For the EB the absorption band at ca.635 nm is relate to the n-π* transition (quinoid form structure) → undoped/ half oxidized PANI structure. • For ES (either with SSA or SPhA) the absorption at ca. 435 nm is due to the presence of localized semiquinone population or the polaron absorption. The long free tail extended to near IR region may be attributed to highly delocalized free electron state of polyaniline doped with these dopants.

P1.8.9 Flexible Ammonia Sensor Based on Polyaniline/Carbon Black Composites Operating at Elevated Temperatures