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The title compound, C 32 H 44 Br 2 CuN 4 O 2 S 2 , was synthesized from 4-bromo- N -(dibutylcarbamothioyl)benzamide ligand and copper(II)acetate. The crystal structure of bis (4-bromo- N -(di- n -butylcarbamothioyl)benzamido) copper(II) complex was determined from single crystal X-ray diffraction studies. It crystallizes in the triclinic space group, P -1 (no. 2) with unit cell dimensions of a = 8.519(10) A, b = 16.64(2) A, c = 25.78(4) A, α = 77.11(3) o , β = 85.59(3) o , γ = 89.46(2) o , Z = 4 and V = 795.8(6) A 3 . The crystal structure is stabilized by weak C-H…N, C-H…S and C-H…Br hydrogen-bonding interactions.

Crystal and molecular structure of bis(4-bromo-N-(di-n-butylcarbamothioyl)benzamido) copper(II) complex