English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The dinuclear compound, [Mn 2 (Pyala) 2 (Dca) 2 (H 2 O)] n ·2H 2 O (1) (Pyala = N -(2-pyridylmethyl)-L-alanine and Dca = dicyanamide anion) has been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction techniques. The crystal data for C 22 H 26 Mn 2 N 10 O 6 : orthorhombic, space group P 2 1 2 1 2 1 (no. 19), a  = 10.3728(8) A, b  = 15.9780(12) A, c  = 16.3585(13) A, V  = 2711.2(4) A 3 , Z  = 4, T  = 198(2) K, μ(MoKα) = 0.989 mm -1 , Dcalc  = 1.559 g/cm 3 , 129607 reflections measured (3.564° ≤ 2Θ ≤ 60.046°), 7923 unique ( R int = 0.0324, R sigma = 0.0155) which were used in all calculations. The final R 1 was 0.0169 (I > 2σ(I)) and wR 2 was 0.0458 (all data). The obtained non-centrosymmetric dinuclear Mn(II) complex contains two unique Mn(II) cations with similar octahedral coordination environment. Photoluminescent measurements on the complex in the solid state show that it displays strong photoluminescence at 442 nm.

Structural and photoluminescent studies of non-centrosymmetric manganese(II) N-(2-pyridylmethyl)-(L)-alanine) dicyanamide