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The main challenge in organic synthesis is the formation of new C-C bonds in order to construct more complex carbon skeletons in a defined arrangement. In contemporary electrochemical publications, such C-C couplings are still a minor subject 1 . Herein we reported an application of a new electrochemical cell which uses graphite powder, silver powder or mix graphite/silver powder in the cathode cavity combined with an aqueous anolyte 2-4

Electrochemical dimerization of benzyl chloride on a powder cathode of silver, graphite or silver-graphite mixture