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1 Brocksom, T. J.; et. al. “Diels-Alder Reactions in the Synthesis of Higher Terpenes,” in Organic Synthesis: Theory and Applications, T. Hudlicky (ed). JAI/Elsevier, Vol. 5, 39-87, 2001. 2 Brocksom, T. J.; Brocksom, U.; Nakamura, J.; Ferreira, M. L. J. Braz. Chem. Soc. 2001, 12, 597. 3 Brocksom, T. J.; Donatoni, M. C.; Uliana, M. P.; Vieira, Y. W.; Quim. Nova, 2010, 33, 2211. Entry R1 R2 diene Yield (%) 1 Me H 3 92 2 Me H 4 71 3 H Me 3 89 4 H Me 4 70

The Diels-Alder reactions of carbomethoxy-p-benzoquinones with simple dienes