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Electrondeficient nitroalkenes exhibit different reactivities in organic synthesis. For example: i) act as dienophiles reacting with dienes to afford nitrocycloadducts derivatives in Diels-Alder reaction; ii) as 1,3-dipolarophiles (DPP) reacting with several 1,3-dipoles in [3+2] cycloadditions and iii) as heterodienes (HD), often in the presence of Lewis acid, to afford cyclic alkyl nitronates in hetero-DielsAlder reactions. 1

proceedings of the 14th brazilian meeting on organic synthesis proceedings

Diastereoselective Multicomponent [4+2]/[3+2] Cycloadditions of gamma-(S)-N,N-dibenzylamine Nitroalkenes Derivatives with Ethyl Vinyl Ether (EVE) and Electron-Poor Alkenes Using Li+- Containing Catalysts.