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This strategy permits a flexibility in the synthetic route. The versatility in introducing different groups at positions R 1 and R 2 as well as on carbon 2 of the oxazolidine ring allows the modulation of steric and eletronic features of the ligand. Some results of the catalytic activity of the phospinites are shown in table 1. The reaction furnished the product in good yields and when ligand 5d was used excellent enantiomeric excesses were obtained.

Highly enantioselective arylation of aromatic aldehydes, promoted by chiral phosphinite ligands