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Tiago de Abreu Siqueira1 Gabriela de Freitas Quandt2 Laura Kunz3 Anthony Credoz4 Rodrigo Iglesias5 Abstract CO2 geological storage is one of the current technologies developed worldwide to reduce industrial emissions of carbon dioxide to the atmosphere. Two main mineral types of deep geological reservoir could be contemplated for CO2 storage: sandstone reservoirs and carbonaceous reservoirs. Geochemical reactivity of a dolomite-calcite mineral compound and magnesite pure mineral was studied with a set of nine experiments per crushed mineral phase with two saline solution and with mQ water and three temperatures: 50°C, 90°C and 150°C. Experiments were performed in batch reactors with 250 bar of CO2 partial pressure during 24h to assess the effect of temperature and salinity in constant CO2 pressure. Solid characterization was performed by XRD and solution analysis by ICP-OES. Acidification of solutions due to CO2 dissolution in water is the main source of reactivity in the system. Proton concentration increases and causes partial dissolution of initial dolomite, calcite and magnesite and release of Ca and Mg cations in solution. Bicarbonate anion (HCO3) concentration also increases due to CO2 dissolution in water and carbonate minerals dissolution. Temperatures of 90°C and 150oC increase the kinetic of reaction and the dissolution of minerals and cations release in solution. New carbonate crystalline phase precipitates as a Ca, Mg solid solution between dolomite and calcite pure poles.

EXPERIMENTAL STUDY OF CARBONATE REACTIVITY IN THE CONTEXT OF CO2 GEOLOGICAL STORAGE