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Asymmetric reactions catalyzed by chiral Bronsted acids are reviewed. In recent years, there has been much effort toward the development of an efficient asymmetric methodology using organocatalysts, and some successful examples of such transformations using chiral Bronsted acid catalysts have been reported to date. Among them, this review describes the asymmetric synthesis of nitrogen-containing compounds using chiral Bronsted acid catalysts, which take advantage of the high affinity for weakly basic substrates such as imines.

Asymmetric Reactions Catalyzed by Chiral Bronsted Acids