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Recent developments in homogeneous asymmetric hydrogenation by use of manufactured transition metal catalysts are remarkable. Their efficiencies are now often comparable or even superior to those of biocatalysts, and an increasing number of transition metal catalyzed asymmetric hydrogenations have been applied to industrial production of optically active compounds. This report deals with asymmetric hydrogenation catalyzed by homogeneous transition metal complexes by putting the emphasis on recent advances in this research field. Especially, asymmetric hydrogenation catalyzed by BINAP-metal complexes has been discussed.

Recent Advances in Asymmetric Hydrogenation by Means of Transition Metal Complexes.