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for which the strong covalency of linear O-Ag-O is regarded as a driving force that overcomes the unfavorable geometry for ionic interactions in lattice.The bond nature of each A-O and M-O in bridge bond A-O-M as well as the two dimensional struc-ture are considered to be key factors for the physical properties of delafossite. Each bond A-O can affect directly on the bond character of the counter bond M-O via common oxygen atom, for instance, the covalency in A-O can be considerably reduced by introducing strong covalent bond M-O. Such a view-point has been frequently adapted in various studies on the electronic properties of delafossite oxides, including the luminescence of linear clusters of O-Cu-O in CuLaO

Preparation of New Ion Conductive Layer-Type Oxide AgxNix/2Ti1-x/2O2(0.60 ≤ x ≤ 1.0)

Preparation of New Ion Conductive Layer-Type Oxide Ag_xNi_x/2Ti_1-x/2O₂(0.60 ≤ x ≤ 1.0)