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While a number of efficientasymmetric palladium-catalyzed asymmetric allylicsubstitutions using chiral ligands have beendeveloped, a drawback is that the majority ofreported reaction conditions are sensitive tomoisture. Therefore, the development of asym-metric allylic substitutions under moisture-stablereaction conditions is still in great demand.Phase-transfer catalysis is an important and use-ful method in organic synthesis.

Palladium-Catalyzed Asymmetric Allylic Alkylation in the Presence of Chiral Cinchonidinium Salts