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) of DIBAL(F) model and carbonyls are in the order of amide < ester < aldehyde < ketone < acidchloride; in the alan-amide adduct, the developed positive charge at carbonyl carbon is expected to be stabilizedby amide resonance, but in the acid chloride adduct it is destabilized by inductive effect of chloride. Howeverthe TS barrier energies (G

MPV-Reduction of C=O bond with Al-substituted-dialkylalan; A Theoretical Study on Relative Reactivity of Various Carbonyl Substrates