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Yong-Nam PakDepartment of Chemistry Education, Korea National University of Education, Chung Buk 363-791, KoreaE-mail: pakyn@knue.ac.krReceived July 2, 2014, Accepted August 8, 2014Matrix-induced mass bias and its effect on the accuracy of isotope ratio measurements have been examined fora quadrupole-based inductively coupled plasma-mass spectrometer (Q ICP-MS). Matrix-induced mass biaseffect was dire ctly proportional to % mass d ifference, and its magnitude varied for element and nebulizer flowrate. For a given element and conditions in a day, the effect was consistent. The isotope ratio of Cd106/Cd114under 200 µg g

Errors in Isotope Dilution Caused by Matrix-induced Mass Bias Effect in Quadrupole Inductively Coupled Plasma-Mass Spectrometry