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E-mail: kimsemail@dankook.ac.krReceived April 23, 2014, Accepted June 3, 2014Key Words : Site-selectivity, Organozinc, Cross-coupling, DibromothiopheneCross-coupling reactions of organometallic reagents havebeen considered to be one of the most efficient syntheticsystems for the preparation of organic functional materials.

Scope and Limitations on the Site-selective Cross-couplings of Arylzincs with 2,3- and 2,5-Dibromothiophene