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toluene sulfonamide (E Merck) was used as received without any further treatment. The solution was prepared in doubly distilled water and was standardized iodometrically. 39,40 Since the solution of chloramine-T is not stable, therefore, the solution was kept in bottles coated black from the outside. The solution of choramine-T, if kept, in dark at refrigerated temperature (~5 oC), the stability is enhanced considerably. Other reagents were either of AnalR or G.R. quality and were used as supplied. Doubly distilled water was employed throughout the kinetic study; second distillation was from alkaline permanganate solution in an all glass assembly. Stoichiometry and Product Analysis. The stoichiometry

Kinetics and Mechanism of Electron Transfer Reaction: Oxidation of Sulfanilic Acid by N-Chloro-p-Toluene Sulfonamide in Acid Perchlorate Medium