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solution is treated with 3,5-di-tert-butylcatechol (3,5-DTBC) at basic condition in the presence of air. Combined information obtainedfrom UV-VIS and EPR measurements could lead the suggestion of the reaction pathway in which the substratemay bind to Cu(II) ions by anti-anti didentate bridging mode.Key Words : Cu(II) complex, N,O-ligand, Self-assembly, Cu(II) EPR, CatecholaseIntroductionMulticopper enzymes containing more than one copperion in their active sites are widely utilized in nature fortransporting copper ions, transferring electrons, activatingdioxygen molecules, and catalyzing many reactions.

Tetrameric Self-Assembly of a Cu(II) Complex Containing Schiff-Base Ligand and Its Unusually High Catecholase-like Activity