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value for reactions which were reported to proceedthrough a concerted mechanism. The Yukawa-Tsuno plot is also linear with ρ = 1.40 and r = 0.47, indicatingthat a negative charge develops partially on the O atom of the leaving group, which can be delocalized to thesubstituent Y through resonance interactions. Thus, the reactions have been proposed to proceed through aconcerted mechanism. The magnitude of the α-effect (i.e., the k

The α-Effect in Nucleophilic Substitution Reactions of Y-Substituted-Phenyl Diphenylphosphinates with HOO-and OH-

The α-Effect in Nucleophilic Substitution Reactions of Y-Substituted-Phenyl Diphenylphosphinates with HOO^-and OH^-