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E-mail: yhrhee@postech.ac.krReceived October 10, 2012, Accepted October 21, 2012Key Words : Herbertene, Herbertenol, Cyclization, Gold, Total synthesisHerbertenes are a family of sesquiterpenoid natural prod-ucts containing 1-aryl-1,2,2-trimethylcyclopentane back-bones possessing two quaternary carbon centers (Figure 1).

bulletin of the korean chemical society

Formal Synthesis of Racemic Herbertene, α-Herbertenol, β-Herbertenol and Herbertenone via Gold(I)-Catalyzed Cyclization of 5-Phenyl-5-siloxy-3-en-1-ynes