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report on copper-mediated cross-coupling of arylboronic acid and amines by Chan and Lam, numerous modifications of copper catalysts, acid or base additives, and solvents have been conducted with the aim of realizing efficient arylation of amines. [Cu(OH)·TMEDA]2Cl2 in the presence of oxidants (O2, TEMPO, and pyridine-N-oxide) was reported as a first catalytic system for amine arylation. 9a,b Subsequently,

All-Purpose Copper Catalyst for Coupling of Ammonium Salts and 1&amp;#x00B0; and 2&amp;#x00B0; Amines with Boronic Acid

All-Purpose Copper Catalyst for Coupling of Ammonium Salts and 1° and 2° Amines with Boronic Acid