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and the “push” provided by the RO groupthrough the resonance interaction. Thus, the enhanced nucleofugality forces the reactions to proceed through aconcerted mechanism. The reactivity-selectivity principle (RSP) is not applicable to the current reactionsystems, since the reaction of the less reactive 4 results in a smaller β

Kinetics and Reaction Mechanism of Aminolyses of Benzyl 2-Pyridyl Carbonate and t-Butyl 2-Pyridyl Carbonate in Acetonitrile