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Division of Bioscience, Dongguk University, Gyeongju 780-714, Korea Received May 18, 2012, Accepted July 16, 2012Two novel Eu(III) complexes with notable properties have been successfully prepared with hydrazone Schiffbase ligands, ( E)-2-hydroxy-N'-[(2-hydroxynaphthalen-1-yl)methylene]benzohydrazide ( 3a) and (E)-4-hydroxy-N'-[(2-hydroxynaphthalen-1-yl)methylene]benzohydrazide (3b). DFT, FMO energy and Mulliken chargedistribution studies of the ligands allowed us to hypothesize that their HC=N, >C=O and -OH (naphthyl) groupswere involved in coordinating with the Eu

bulletin of the korean chemical society

Synthesis, Antioxidant Activity and Fluorescence Properties of Novel Europium Complexes with (E)-2- or 4-hydroxy-N'-[(2-hydroxynaphthalen-1-yl)methylene]benzohydrazide Schiff Base