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cathodes upon oxidation of electrolyte during electrochemicalcycling was investigated. Information on the important factors for film formation on the cathode can facilitatethe design of additives that improve the properties of the cathode. Pyrazole is added to the electrolyte becauseit is readily oxidized to form a surface film on the cathode. The results of differential scanning calorimetry andFourier transform infrared spectroscopy (FTIR) showed that the active material played a dominant role in theinterfacial film formation with the electrolyte. Carbon black played a negligible role in the surface filmformation. Key Words : Li-ion battery, Li(Ni

bulletin of the korean chemical society

Study on the Dominant Film-Forming Site Among Components of Li(Ni1/3Co1/3Mn1/3)O2Cathode in Li-ion Batteries