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Although most of these methods provide good yields, manyof them suffer from one or more disadvantages. Thus mole-cular bromine, the simplest brominating agent, suffers fromseveral drawbacks: it is hazardous and difficult to handle andto maintain the stoichiometric ratio during the reaction.Other problems associated with these methods are tediouswork-up procedures and long reaction times. N-Bromosaccharin has been used as oxidants and bromi-nating agent. It is a white powder and easy to handle.

Selective Monobromination of 1,3-Diones with N-Bromosaccharin/Mg(ClO4)2System in Solution and under Solvent-Free Conditions

Selective Monobromination of 1,3-Diones with N-Bromosaccharin/Mg(ClO₄)₂System in Solution and under Solvent-Free Conditions