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The four crystallographically inequivalent atoms A, B, O, and O' in the face centered cubic unit cell occupy the 16d, 16c, 48f, and 8b sites of the Fd3m space group, respectively. The ideal pyro-chlore structure is composed of two types of cation-oxygen sublattices: one is a corner sharing tetrahedral network compos-ed of A atoms with an O' atom in the center of each tetrahedron, and the other is another tetrahedral network of B atoms with each B atom coordinated quasi-octahedrally by six O atoms. This type of tetrahedral network is called the pyrochlore lattice. The compounds where A is a tr ivalent and B a tetravalent ca-tion (A

Factors Affecting the Superconducting Transition Temperatures of β-Pyrochlore Oxides AOs2O6(A=K, Rb and Cs)

Factors Affecting the Superconducting Transition Temperatures of β-Pyrochlore Oxides AOs₂O₆(A=K, Rb and Cs)