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E-mail: parkyong@konkuk.ac.krReceived August 26, 2011, Accepted September 5, 2011Key Words : Dynamic kinetic resolution, Nucleophilic substitution, Malic acid, Chiral auxiliary, AsymmetricsynthesisChiral auxiliary-mediated dynamic resolution of α-haloesters has been known as an effective method for asym-metric synthesis of α-heteroatom substituted carboxylic acidderivatives.

Asymmetric Synthesis of 3-Substituted Morpholinones and Piperazinones by L-Malate-mediated Dynamic Kinetic Resolution of α-Bromo Esters