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” conformation (“1,3,5-up/2,4,6-down” conformation) to avoid otherwise increased steric repulsion between the vicinal substituents of the benzene frame. Use of such sterically bulky subunits within a molecule to enable it to adopt a thermodynamically favored conformation with mini-mum steric interactions has been dubbed as “steric gearing.”

Chiral Discrimination of α-Chiral Ammonium Ions by Sterically Geared Chiral Tripodal Oxazolines