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Aromatic aldehydes are efficiently self-condensed into α-hydroxy carbonyl compounds by polystyrene-supported ammonium cyanide as an excellent organocatalyst in C-C bond formation. The reaction proceeds in water under mild reaction conditions. The polymeric catalyst can be easily separated by filtration and reused several times without appreciable loss of activity.

Polymer Supported Cyanide as an Efficient Catalyst in Benzoin Condensation: An Efficient Route to α-Hydroxy Carbonyl Compounds