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Although the N-alkylation of amines is deceptively simple, this method has some drawback due to the formation of overalkylation products such as secondary amines, tertiary amines, and quaternary ammonium salts. There is also limitation due to stability of primary amine and availability and isolation problem for multiple amines derivatives. On the other hand, azides have proven to be useful as a kind of protecting group and precursor of amine compound in chemical synthesis.

Staudinger /Aza-Wittig Click Chemistry for Synthesis of Dendrimers Using Frechet Type Dendritic Benzyl Azides