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These new breed of metal complexes, small cousins of metal complexes with large ligands, often show unique structures and photochemical properties. Particularly the methylidene complexes often show markedly distorted structures for one of the hydrogen atoms to position close to the metal atom (agostic structure).

bulletin of the korean chemical society

Agostic Interaction of the Smallest Zirconium Methylidene Hydride: Reproduction of the Distorted Structure Experimentally Observed in Matrix Infrared Spectra