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We have further demonstrated that they are not only versatile ligands in a Cu-catalyzed cyclopropanation of styrene and Pd-/Mo- catalyzed allylic alkylation of allyl acetates to achieve a com-plete diastereoselectivity but also nucleophilic catalysts for highly regioselective ring-opening of epoxides.

Iminophosphoranylferrocenes as New Nucleophilic Organocatalysts for Regioselective Ring-opening of Epoxides