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8 3 4 (61%) (17%) (3) Because of its diverse application in industry and compatibility in green chemistry, the electro organic synthesis (E.O.S.) is expected to provide the important organic synthetic tools in a near future. The brief review about the E.O.S. was introduced by us. Our continuing efforts to develop the E.O.S. utilizing alternated Mg electrodes, the synthetic routes from the nitro aromatic compounds to the azo compounds and the reductive coupling of aromatic mono halides were reported by our laboratory. For further expansion of the our E.O.S. reaction, the benzal bromide 1 was exposed to our optimized aromatic mono halide coupling reaction. The important reaction conditions were the following : Mg metal for both of anode and cathode and LiClO4 as an electrolyte at the room temperature under a constant current (current density = 42 mA/cm). The current of anode and cathode were altered at an interval of 30 second in order to minimize the consumption of metal. The two major spots were separated from the reaction residue in a low yield. They were characterized by TLC and by spectroscopic methods with the authentic samples. (Eq. 1)

Electro Organic Synthesis Utilizing Mg Electrodes (III) - E.O.S. Hydrogenation of Stilbene Equivalent to Catalytic Hydrogenation -