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= 4, 5, 6, 7 and 11) were obtained ingood yields.The present reaction sequence, organoaluminum-promot-ed Beckmann rearrangement of oxime mesylate, allylationreaction with 2-(trimethylsilylmethyl)allyllithium, and Man-nich reaction, provides a versatile and useful syntheticmethod for 1-azabicylo[n.4.0]alkanes.

Facile Synthesis of Various 1-Azabicyclo[n.4.0]alkanes via Beckmann Rearrangement/Allylsilane Cyclization