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Thus the terdentate chelation in the complexesinhibits both dissociation of the phosphine (or nitrogen)groups and reductive elimination of the aryl group. Such aremarkably rigid framework provided by the pincer typeligands, therefore, enhances thermal stability of resultingcomplexes, and may have catalytic implication in a widerange of homogeneous catalysis.

Bis(imino)aryl Complex of Nickel(II): N,C,N-Pincer Type Complex, (2,6-(2,6-Et2PhN=CH)2C6H3)NiBr

Bis(imino)aryl Complex of Nickel(II): N,C,N-Pincer Type Complex, (2,6-(2,6-Et₂PhN=CH)₂C₆H₃)NiBr