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benzoyl)monobenzotetraazacyclo[14]annulenepalladium(II), Spectral and electrochemi-cal properties, X-ray structureSeveral tetraazaannulenenickel(II) complexes have beensynthesized by a one-step template method in a high yield.The replacement of the central metal atom, by othertransition metals, is possible only by demetallating nickelcomplexes. These complexes have been known to possessdifferent chemical and thermal stabilities and electrocata-lytic activities by substituents at the methine sites such as

bulletin of the korean chemical society

Synthesis of Asymmetric Dibenzoylated Tetraazacyclo[14]annulenepalladium(II) Complexes: Structure of 3,10-Di(p-methylbenzoyl)-2,4,9,11-tetramethyl-1,5,8,12-monobenzotetraazacyclo[14]annulenepalladium(II)