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New liquid-crystalline biphenyl carboxylates with an achiral swallow-tail derived from 1,3-dialkoxy-2-propanol ] where R is methyl, ethyl, propyl, butyl, , and were prepared. These achiral liquid crystals having 1,3-dialkoxy-2-propyl moieties exhibit diverse phase sequences [I-SmA-(SmC)-(SmCalt)-Cr] depending on the substituent R group of the swallow-tail. The compounds carrying a fluorinated swallow-tail exhibit antiferroelectric-like smectic C phases, and their temperature ranges are broader than the corresponding non-fluorinated swallow-tailed ones.

Synthesis and Mesomorphic Properties of New Swallow-tailed Liquid Crystals Derived from 1,3-Dialkoxy-2-propanols