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Metalloporphyrins have been extensively studied due to their roles in many biological processes, such as oxygen carriers in haemoglobin and myoglobin and as enzyme model systems. The reactivity of synthetic metalloporphyrins with various axial liagnds has also been intensively studied for a few years, since it has been recently shown that anionic ligands of iron (III) porphyrin as well as manganese (III) porphyrin complexes play an important role in the catalytic oxygenation of hydrocarbons. On the other hand, the Cd(II) ion is an important transition metal element and many cadmium(II) porphrin complexes have been studied. However, till now, to the best of our knowledge, the Cd(II) porphhrin complexes having axial ligands are little. Recently, in our laboratory, the title complex of (α-aminopyridineN)-(5,10,15,20-tetraphenylporphyrinato) cadmium(II) acetone solvate, in which α-aminopyridine is used as an axial ligand, has been synthesized. Natural population analysis on the title complex also has been performed by using density functional theory at B3LYP/LANL2DZ level. Herein, we report the experimental results as well as the theoretical calculated results of the title complex.

Synthesis, Characterization and Crystal Structure of (α-Aminopyridine-N)-(5,10,15,20-tetraphenylporphyrinato) Cadmium(II) Acetone Solvate