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The rich chemistry of complexes of dicompartmental ligands binding identical metals and to a lesser extent different metals has been applied to the investigation of magnetic exchange interactions between the two metal ions, the stabilization of mixed-valent species, and the activation of small molecules. Particularly, significant examples (I and II) of this type are planar ligands with imine or amine donors and bridging phenolic oxygens, which are usually referred to as Robson-type ligands. The complexes formed from these macrocyclic ligands are also used as models for protein-metal binding sites in biological systems, as synthetic ionophores, as therapeutic reagents in chelate therapy for treatment of metal toxication, in catalysis and to investigate the mutual influence of two metal centers on their physicochemical properties.

Synthesis and Characterization of Oxa-azamacrocyclic Dinuclear Cu(II) Complex Containing Aqua Ligands