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The rational construction of functional coordination polymers with specific motifs in organic solvents is a fruitful field since the materials have various potential applications such as molecular separation, harmful materials adsorption, molecular containment, ion exchange, molecular recognition, and luminescent sensing. Solubility of reactants is one of the most significant factors on the formation of such molecular materials. We have demonstrated that various pyridyl ligands are useful spacer for desirable skeletons. Among various skeletal structures, some diamonoid networks are of great interest in the field of supramolecular chemistry since they may have vacant spaces, giving rise to interpenetration or guest inclusion. Such diamonoid networks may be obtained from the tetrahedral component through metal coordination, hydrogen bonding, donoracceptor interactions, or van der Waals interactions. Angles and lengths of potential bidentate spacers play key roles in the molecular construction of diamonoid materials. In an effort to scrutinize the solubility effects on molecular constructions, the slow reaction of AgCF3SO3 with a mixture of bis(3-pyridoxy)benzene (bpob) as a spacer and βcyclodextrin as a water-solubilizing additive was carried out. The bpob is a potential linear N-donor bidentate spacer and Ag(I) ion has been employed as the unit of a potential tetrahedral geometry.

An Interpenetrating Diamonoid Coordination Polymer of Ag(I) with Bis(3-pyridoxy)benzene in Aqueous Media